One of the main issues I find is here is that because houses are built with single skin brick walls, they absorb the heat all day long, and then during the evening and at least the early part of the night, give that heat off into the room that you are trying to keep cool with AC. So even by extracting the hot air with fans, keeping windows open or using the AC, the walls act like radiators keeping the room hot. All of which of course makes a rather inefficient use of electric etc.
The roof has a reflective liner under the tiles, and the bedroom ceilings seem to have cooled down well by 11.00pm, whereas the external walls are still giving off heat well past midnight.
I have done what I can with shading the outside of the house with trees etc, (though that is limited); also using sun liners on the curtains (which of course only helps on the windows, which are a only a small part/area of the walls exposed to the sun). I have toyed with the idea of using external sun shades, but don't want to make the house look too much like a "shanty", and there would be difficulties in where and how to position them.
The only other thing I can think of would be to construct some form of additional insulating second wall, e.g. create an internal partition type wall with a reflective insulated liner inside, between the single skin brick wall and the room! However that all strikes me as both costly and untidy, and probably not worth the hassle or cost for the end result.